Comparative Assessment of Heavy Metal Contamination in Surface Soils across Industrial, Urban, Rural, and Agricultural Areas

Authors

  • Zahid Hassan Tarar Soil & Water Testing Laboratory, M.B.Din
  • Nadia Gul Government Gordon Graduate College, Rawalpindi
  • Muhammad Shoaib Aslam Soil & Water Testing Laboratory, Jhelum
  • Talha Murad Soil & Water Testing Laboratory, Gujranwala
  • Arif Hussain Department of Soil and Environmental Sciences, Ghazi University, Dera Ghazi Khan
  • Muhammad Saleem Soil & Water Testing Laboratory, Lodhran
  • Saima Nazar Soil & Water Testing Laboratory, Hafizabad
  • Sajid Ali Soil &Water Testing Laboratory Jhang
  • Irfan Ahmad Saleem Soil & Water Testing Laboratory, Gujrat
  • Saiqah Toor Soil & Water Testing Laboratory, Gujrat
  • Nadeem Hussain Soil Fertility Section Sargodha
  • Saeed Ur Rehman Soil & Water Testing Laboratory, Bahawalpur
  • Sher Afzal Soil & Water Testing Laboratory, Jhelum
  • Waqar Illahi Soil & Water Testing Laboratory, Rajanpur

DOI:

https://doi.org/10.55627/agrivet.004.01.01114

Keywords:

Heavy Metals, Industrial, Urban, Rural, Agriculture, Nowshera

Abstract

This study investigates heavy metal contamination in surface soils across industrial, urban, rural, and agricultural land use types in Nowshera District, Pakistan. The research addresses the critical issue of soil contamination resulting from anthropogenic activities such as industrial emissions, urban expansion, and agricultural intensification. A total of 76 soil samples were collected from 34 sites representing diverse land use types and analyzed for heavy metals, including lead (Pb), cadmium (Cd), zinc (Zn), copper (Cu), and nickel (Ni), using flame atomic absorption spectrophotometer. Physicochemical properties, including pH, organic matter content, and salinity, were also measured to understand their influence on heavy metal distribution. Results indicate significant variations in heavy metal concentrations across land use types, with industrial soils showing the highest contamination levels. For instance, the mean Pb concentration in industrial soils (175.6 mg/kg) was nearly four times higher than in rural soils (46.3 mg/kg). Similarly, Zn levels were significantly elevated in industrial areas, averaging 430.6 mg/kg compared to 122.7 mg/kg in rural soils. Urban soils exhibited moderate contamination, driven by vehicular emissions and construction activities, while agricultural soils showed lower overall contamination but localized hotspots due to agrochemical use. Pollution indices such as the Geo-accumulation Index (Igeo) and Pollution Load Index (PLI) confirmed anthropogenic contributions to heavy metal accumulation. Spatial analysis using GIS identified contamination hotspots, particularly in industrial and urban areas, highlighting the need for targeted remediation strategies. Multivariate statistical analyses, including Principal Component Analysis (PCA) and Cluster Analysis (CA), revealed distinct groupings of metals based on anthropogenic and lithogenic sources. These findings underscore the critical influence of land use practices on soil contamination dynamics. This study provides a comprehensive evaluation of heavy metal contamination in Nowshera’s soils, offering valuable insights for sustainable land management and pollution mitigation strategies. The research emphasizes the importance of integrating scientific assessments with policy interventions to address the ecological and health risks posed by heavy metal pollution.

References

Adhikari, K., Mancini, M., Libohova, Z., Blackstock, J., Winzeler, E., Smith, D. R., Owens, P. R., Silva, S. H., & Curi, N. 2024. Heavy metals concentration in soils across the conterminous USA: Spatial prediction, model uncertainty, and influencing factors. 1 The Science of the Total Environment, 919, 170972.

Akter, S., Jolly, Y. N., Kabir, J., Mamun, K. M., Rahman, M. O., Hasan, M., Sarkar, M. H., Begum, B. A., Abedin, M. J., Tushar, S. I., Fahad, S. M., Rahman, M. S., & Khandaker, M. U. 2023. Heavy metal contamination of surface soils by anthropogenic activities: concomitant ecological and health risk assessment. International Journal of Environmental & Analytical Chemistry, 1–21.

Bai, Y., Zhang, Y., Liu, X., & Wang, Y. 2023. The spatial distribution and source apportionment of heavy metals in soil of Shizuishan, China. Environmental Earth Sciences, 82(21).

Basir, M. S., Khan, R., Akhi, S. Z., Ullah, A. A., Islam, M. A., Naher, K., Idris, A. M., Khan, M. H. R., Aldawood, S., & Saha, N. 2024. Source specific sedimentary response towards the differential anthropogenic impacts in terms of potentially toxic elements in an urban river. Marine Pollution Bulletin, 203, 116425.

Bibi, M., Rashid, J., Iqbal, A., & Xu, M. 2023. Multivariate analysis of heavy metals in pharmaceutical wastewaters of National Industrial Zone, Rawat, Pakistan. Physics and Chemistry of the Earth Parts a/B/C, 130, 103398.

Buat-Menard, P., & Chesselet, R. 1979. Variable influence of the atmospheric flux on the trace metal chemistry of oceanic suspended matter. Earth and Planetary Science Letters, 42(3), 399-411.

Bux, R. K., Haider, S. I., Batool, M., Solangi, A. R., Shah, Z., Karimi-Maleh, H., & Sen, F. 2021. Assessment of heavy metal contamination and its sources in urban soils of district Hyderabad, Pakistan using GIS and multivariate analysis. International Journal of Environmental Science and Technology, 19(8), 7901–7913.

Cao, B., Sun, Z., Bai, D., Kong, L., Zhang, X., Chen, J., & Chen, D. 2024. The Identification of Soil Heavy Metal Sources and Environmental Risks in Industrial City Peri-Urban Areas: A Case Study from a Typical Peri-Urban Area in Western Laizhou, Shandong, China. Sustainability, 16(11), 4655.

Chen, X., Zhang, H., & Wong, C. U. I. 2024. Spatial distribution characteristics and pollution evaluation of soil heavy metals in Wulongdong National Forest Park. Scientific Reports, 14(1).

Chudasama, T., Dangar, K., Gadhvi, K., Vyas, S., & Dudhagara, D. 2024. Multivariate statistical analysis of bioavailability of heavy metals and mineral characterization in selected species of coastal flora. Scientific Reports, 14(1).

Emumejakpor, S. I., & Adewumi, A. J. 2023. Comparative analysis of heavy metal concentrations and potential health risks across varied Land usezones in Ado-Ekiti, southwest Nigeria. Acadlore Transactions on Geosciences, 2(2), 113–131.

Facchinelli, A., Sacchi, E., & Mallen, L. 2001. Multivariate statistical and GIS-based approach to identify heavy metal sources in soils. Environmental Pollution, 114(3), 313-324.

Feng, Z., Chen, W., Meng, Y., Lu, H., Shi, X., & Zhang, J. 2024. Spatial variability and source analysis of soil heavy metals: A case study of the key planting area of special agricultural products in Cangxi County, China. PLoS ONE, 19(5), e0303387.

Herath, D., Pitawala, A., Gunatilake, J., & Iqbal, M. C. M. 2018. Using multiple methods to assess heavy metal pollution in an urban city. Environmental Monitoring and Assessment, 190(11).

Hošek, M., Pavlíková, P., Šoltýs, M., Tůmová, Š., & Grygar, T. M. 2024. Distinguishing geogenic load and anthropogenic contribution to soil contamination in mineralised mountain landscape of Ore Mountains (Czech Republic) using cumulative distribution functions. Land, 13(2), 218.

Jiang, X., Wang, X., Liu, Y., Huang, Y., & Huang, X. 2024. Heavy metal changes related to land use changes in a karst area: a case study in Changshun, Guizhou Province, China. Frontiers in Environmental Science, 12.

Khalid, S., Shahid, M., Niazi, N. K., Murtaza, B., Bibi, I., & Dumat, C. 2016. A comparison of technologies for remediation of heavy metal contaminated soils. Journal of Geochemical Exploration, 1 182, 247–268.

Khan, S. A., Suleman, M., & Asad, M. (2017). Assessment of pollution load in marble waste water in Khairabad, District Nowshera, Khyber Pukhtunkhwa, Pakistan. Int. J. Economic and Environmental Geology, 8(2), 35-39.

Korkanç, S. Y., Korkanç, M., & Amiri, A. F. 2024. Effects of land use/cover change on heavy metal distribution of soils in wetlands and ecological risk assessment. The Science of the Total Environment, 923, 171603.

Li, W., Zhang, S., Gao, F., Chen, Z., Jiang, J., & Sun, G. 2024. Spatial distribution, sources apportionment and risk assessment of heavy metals in the Changchun black soil area, China. Journal of Hazardous Materials Advances, 13, 100402. Muller, G. 1969. Index of geoaccumulation in sediments of the Rhine River. Geology Journal, 2(3), 108-118.

Pujari, M., & Kapoor, D. 2020. Heavy metals in the ecosystem: Sources and their effects. In Elsevier eBooks (pp. 1–7).

Qazi MA, Khan MSA, Ahmad F, Qamar MJ. SFRI-Guide-2: Soil and Water Analysis Manual. Directorate of Soil Fertility Research Institute, Department of Agriculture, Punjab, Lahore, 2021

Rana, M. S., Wang, Q., Wang, W., Enyoh, C. E., Islam, M. R., Isobe, Y., & Kabir, M. H. 2024. Sources, Distribution, and Health Implications of Heavy Metals in Street Dust across Industrial, Capital City, and Peri-Urban Areas of Bangladesh. Atmosphere, 15(9), 1088

Rehman, T. ur, Alam, T., Kashif Aziz, M., Shahzad, M., Bashir, M., Hassan, J., & Sadaf, R. (2024). Textile effluent impact on rice (Oryza sativa L.) growth attributes in Sandy Clay loam soil. Journal of Agriculture and Veterinary Science, 3(2), 245–253.

Tomlinson, D. L., Wilson, J. G., Harris, C. R., & Jeffrey, D. W. 1980. Problems in the assessment of heavy-metal levels in estuaries and the formation of a pollution index. Helgoländer Meeresuntersuchungen, 33(1-4), 566-575.

Turekian, K. K., & Wedepohl, K. H. 1961. Distribution of the elements in some major units of the Earth’s crust. Geological Society of America Bulletin, 72(2), 175-192.

U.S. EPA. 2007. Method 3051A (SW-846): Microwave Assisted Acid Digestion of Sediments, Sludges, and Oils, Revision 1. Washington, DC.

Zhang, D. M., Teng, Q., Zhang, D., Jilani, G., Ken, W. M., Yang, Z. P.,Alam,T.,Ikram,M & Iqbal,Z.(2021). Performance and microbial community dynamics in anaerobic continuously stirred tank reactor and sequencing batch reactor (CSTR-SBR) coupled with magnesium-ammonium-phosphate (MAP)-precipitation for treating swine wastewater. Bioresource Technology, 320, 124336.

Downloads

Published

2025-03-27

Issue

Section

Research Articles

How to Cite

Comparative Assessment of Heavy Metal Contamination in Surface Soils across Industrial, Urban, Rural, and Agricultural Areas (Z. H. Tarar, N. Gul, M. S. Aslam, T. Murad, A. Hussain, M. Saleem, S. Nazar, S. Ali, I. A. Saleem, S. . Toor, N. Hussain, S. U. Rehman, S. Afzal, & W. Illahi, Trans.). (2025). Journal of Agriculture and Veterinary Science, 4(1), 63-74. https://doi.org/10.55627/agrivet.004.01.01114

Similar Articles

31-33 of 33

You may also start an advanced similarity search for this article.

Most read articles by the same author(s)